Nearly all of the bioballs in existence are made from plastic. I've supplied a photo of them here:
In most applications the bioballs are used in a trickle tower configuration and are never submerged in the water, such as the bioballs in the following filter:

The water is showered down from the top and exits the bottom. I believe the sidepipe in this picture is used for purging and is not included when building a similar filter for a pond.
The bioballs are therefore better used after any prefiltration because when the bioballs are fed with pre-cleaned water (meaning some sponge has already removed large bits of leaves etc and is only passing pond water through) they will work much more effectively.
If used before the filters, you will find the need to clean them regularly.
Because plastic bioballs take some time (4-8 weeks in my case,as well as others) washing the bioballs will clear any good biological film that has grown on the bioballs. Therefore as before, place them in an area where you are unlikely to remove them at all for cleaning (which you shouldn't do at all).
If you wish to submerge the bioballs I believe they won't work as well as they would in a wet/dry filter (or in large pond filtration applications "trickle towers") because as I have tried, when I first cleaned the bioballs (before use) the way the water collided down through the bioballs it created a lot of airation in between the bioball media (which is good for cultivating the positive bacteria (in this case aerobic bacteria). I would more likely try and source a different biomedia best used in a submerged application like ceramic rings.
In the alternative, you could always look into constructing a new filtration system to be situated in the open area, and have a new submersible solids handling pump feed that filter system instead. You would therefore have two filter systems on the pond, and you wouldn't need to cut into the old filtration system to fit additional filters. You could make the second filtration system be based on "trickle towers" (running two barrels/containers) with one as a settlement tank, and the other as a trickle tower.
Regards,
Aquaman